周其林教授课题组

400-6699-117转1000

167. Yuan-Yuan Ren, Shou-Fei Zhu,* and Qi-Lin Zhou.* Chiral Proton-Transfer Shuttle Catalysts for Carbene Insertion Reactions. Org. Biomol. Chem. 2018, DOI: 10.1039/C8OB00473K.(Review)

166. Li-Jun Xiao, Chao-Yue Zhao, Lei Cheng, Bo-Ya Feng, Wei-Min Feng, Jian-Hua Xie, Xiu-Fang Xu,* and Qi-Lin Zhou.* Nickel(0)-Catalyzed Hydroalkenylation of Imines with Styrene and Derivatives. Angew. Chem. Int. Ed. 2018, 57, 3396-3400.

165. Meng-Yang Hu, Qiao He, Song-Jie Fan, Zi-Chen Wang, Luo-Yan Liu, Yi-Jiang Mu, Qian Peng*, and Shou-Fei Zhu*. Ligands with 1,10-phenanthroline scaffold for highly regioselective iron-catalyzed alkene hydrosilylation. Nat. Commun. 2018, 9, 221.

164. Li-Jun Xiao, Lei Cheng, Wei-Min Feng, Mao-Lin Li, Jian-Hua Xie, and Qi-Lin Zhou*. Nickel(0)-Catalyzed Hydroarylation of Styrenes and 1,3-Dienes with Organoboron Compounds. Angew. Chem. Int. Ed. 2018, 57, 461-464.

163. Xiao-Dong Zuo, Shu-Min Guo, Rui Yang, Jian-Hua Xie,* and Qi-Lin Zhou. Asymmetric Total Synthesis of Gracilamine and Determination of Its Absolute Configuration. Org. Lett. 2017, 19, 5240-5243.

162. Guo-Peng Wang, Meng-Qing Chen, Shou-Fei Zhu,* and Qi-Lin Zhou*. Enantioselective Nazarov cyclization of indole enones cooperatively catalyzed by Lewis acids and chiral Brønsted acids. Chem. Sci. 2017, 8, 7197-7202.

161. Yun-Ting Liu, Lin-Ping Li, Jian-Hua Xie* and Qi-Lin Zhou. Divergent Asymmetric Total Synthesis of Mulinane Diterpenoids. Angew. Chem., Int. Ed. 2017, 56, 12708-12711.

160. Ji-Min Yang, Zi-Qi Li; Shou-Fei Zhu.* Progresses on the Application of Stable Borane Adducts in the Synthesis of Organoborons. Chin. J. Org. Chem. 2017, 37, 2481-2497.

159. Min-Jie Zhou, Shou-Fei Zhu and Qi-Lin Zhou.* Copper-catalyzed Mannich-type oxidative β-functionalization of tertiary amines. Chem. Commun., 2017, 53, 8770-8773.

158. Xiao-Dong Zuo, Shu-Min Guo, Rui Yang, Jian-Hua Xie,* and Qi-Lin Zhou.* Bioinspired Enantioselective Synthesis of Crinine-type Alkaloids via Iridium-Catalyzed Asymmetric Hydrogenation of Enones.Chem. Sci. 2017. 8. 6202-6206.

157. Yun-Ting Liu, Ji-Qiang Chen, Lin-Ping Li, Xin-Yang Shao, Jian-Hua Xie,* and Qi-Lin Zhou. Asymmetric Hydrogenation of Tetrasubstituted Cyclic Enones to Chiral Cycloalkanols with Three Contiguous Stereocenters. Org. Lett. 2017, 19, 3231-3234.

156. Huan Xu, Yi-Pan Li, Yan Cai, Guo-Peng Wang, Shou-Fei Zhu*, Qi-Lin Zhou*. Highly Enantioselective Copper- and Iron-Catalyzed Intramolecular Cyclopropanation of Indoles. J. Am. Chem. Soc. 2017, 139, 7697-7700. (Huan Xu, Yi-Pan Li and Yan Cai contributed equally)

155. Shou-Fei Zhu*, Qi-Lin Zhou*. Iridium-Catalyzed Asymmetric Hydrogenation of Unsaturated Carboxylic Acids. Acc. Chem. Res. 2017, 50, 988-1001.

154. Qing-Qing Cheng, Ji-Min Yang, Huan Xu, Shou-Fei Zhu*. Iron-Catalyzed Carbenoid Insertion into C(sp3)–H Bonds. Synlett. 2017, 28, 1327-1330.

153. Ji-Min Yang, Zi-Qi Li, Mao-Lin Li, Qiao He, Shou-Fei Zhu*, Qi-Lin Zhou*. Catalytic B–H Bond Insertion Reactions Using Alkynes as Carbene Precursors. J. Am. Chem. Soc, 2017, 139, 3784-3789.

152. Deng-Hui Bao, Xue-Song Gu, Jian-Hua Xie*, Qi-Lin Zhou*. Iridium-Catalyzed Asymmetric Hydrogenation of Racemic β-Keto Lactams via Dynamic Kinetic Resolution. Org. Lett. 2017, 19, 118-121.

151. Mao-Lin Li, Shuang Yang, Xun-Cheng Su, Hui-Ling Wu, Liang-Liang Yang, Shou-Fei Zhu*, Qi-Lin Zhou*. Mechanism Studies of Ir-Catalyzed Asymmetric Hydrogenation of Unsaturated Carboxylic Acids, J. Am. Chem. Soc. 2017, 139, 541-547. (Mao-Lin Li and Shuang Yang contributed equally to this work)

150. Xiao-Hui Yang, Hai-Tao Yue, Na Yu, Yi-Pan Li, Jian-Hua Xie*, Qi-Lin Zhou*. Iridium-Catalyzed Asymmetric Hydrogenation of Racemic α-Substituted Lactones to Chiral Diols. Chem. Sci. 2017, 8, 1181-1184.

149. Shuang Yang, Wen Che, Hui-Ling Wu, Shou-Fei Zhu*, Qi-Lin Zhou*. Neutral Iridium Catalysts with Chiral Phosphine-Carboxy Ligands for Asymmetric Hydrogenation of Unsaturated Carboxylic Acids. Chem. Sci. 2017, 8, 1977-1980

148. Ming-Lei Yuan, Jian-Hua Xie, Qi-Lin Zhou*. Boron Lewis Acid Promoted Ruthenium-Catalyzed Hydrogenation of Amides: An Efficient Approach to Secondary Amines. ChemCatChem. 2016, 8, 3036-3040.

147. Xiao-Guang Song, Yuan-Yuan Ren, Shou-Fei Zhu*, Qi-Lin Zhou*. Enantioselective Copper-Catalyzed Intramolecular N-H Bond Insertion: An Efficient Synthesis of Chiral 2-Carboxy Tetrahydroquinolines. Adv. Synth. Catal. 2016, 358, 2366-2370.

146. Ming-Lei Yuan, Jian-Hua Xie, Shou-Fei Zhu, Qi-Lin Zhou*. Deoxygenative Hydrogenation of Amides Catalyzed by a Well-Defined Iridium Pincer Complex. ACS. Catal. 2016, 6, 3665-3669.

145. Jing Hou, Ming-Lei Yuan, Jian-Hua Xie, Qi-Lin Zhou*. Nickel-Catalyzed Hydrocarboxylation of Alkynes with Formic Acid. Green Chem. 2016, 18, 2981-2984

144. Yang Liu, Li-Jie Cheng, Hai-Tao Yue, Wen Che, Jian-Hua Xie*, Qi-Lin Zhou. Divergent enantioselective synthesis of hapalindole-type alkaloids using catalytic asymmetric hydrogenation of a ketone to construct the chiral core structure. Chem. Sci. 2016, 7, 4725-4729 (Yang Liu and Li-Jie Cheng contributed equally to this work)

143. Liu-Yang Pu, Ji-Qiang Chen, Mao-Lin Li, Yao Li, Jian-Hua Xie*, Qi-Lin Zhou. Enantioselective Construction of Chiral 2,3-cis-Dimethyl-dihydrobenzofuran with an All-Carbon Quaternary Center: An Efficient Approach to (+)/(-)-PI-220 and (+)-3-epi-Furaquinocin C. Adv.Synth. Catal. 2016. 358, 1229-1240. (Liu-Yang Pu and Ji-Qiang Chen contributed equally to this work)

142. Han Lin, Li-Jun Xiao, Min-Jie Zhou, Hong-Ming Yu, Jian-Hua Xie*, Qi-Lin Zhou*. Enantioselective Approach to (−)-Hamigeran B and (−)-4-Bromohamigeran B via Catalytic Asymmetric Hydrogenation of Racemic Ketone To Assemble the Chiral Core Framework. Org. Lett. 2016,18, 1434-1437.

141. Yan-Bo Yu, Lei Cheng, Yi-Pan Li, Yue Fu, Shou-Fei Zhu*, Qi-Lin Zhou*. Enantioselective iridium-catalyzed hydrogenation of β,β-disubstituted nitroalkenes. Chem. Commun., 2016, 52, 4812-4815

140. Li-Jun Xiao, Xiao-Ning Fu, Min-Jie Zhou, Jian-Hua Xie, Li-Xin Wang, Xiu-Fang Xu*, Qi-Lin Zhou*. Nickel-Catalyzed Hydroacylation of Styrenes with Simple Aldehydes: Reaction Development and Mechanistic Insights. J. Am. Chem. Soc. 2016, 138, 2957-2960.

139. Ji-Min Yang, Yan Cai, Shou-Fei Zhu*, Qi-Lin Zhou. Iron-catalyzed arylation of α-aryl-α-diazoesters. Org. Biomol. Chem. 2016. 14, 5516-5519

138. Qi-Lin Zhou*, Transition-Metal Catalysis and Oragnocatalysis: Where Can Progress Be Expected? Angew. Chem. Int. Ed. 2016, 55, 5352-5353 (Editorial)

137. Jun-Xia Guo, Ting Zhou, Bin Xu, Shou-Fei Zhu*, Qi-Lin Zhou. Enantioselective synthesis of α-alkenyl α-amino acids via N–H insertion reactions, Chem. Sci. 2016, 7, 1104-1108.

136. Jian-Hua Xie and Qi-Lin Zhou.Creation of chiral materials: Yesterday, today and tomorrow.Chinese Science Bulletin. 2015, 60, 2679.

135. Jian-Hua Xie and Qi-Lin Zhou. Catalytic Asymmetric Hydrogenation of Substituted Ketones and Aldehydes via Dynamic Kinetic Resolution:Efficient Approach to Chiral Alcohols. Aldrichimica Acta,2015, 48, 33.

134. Bin Xu, Mao-Lin Li, Xiao-Dong Zuo, Shou-Fei Zhu *, and Qi-Lin Zhou. Catalytic Asymmetric Arylation of α-Aryl-α-diazoacetates with Aniline Derivatives. J. Am. Chem. Soc, 2015, 137, 8700-8703.

133. Deng-Hui Bao, Hui-Ling Wu, Chao-Lun Liu, Jian-Hua Xie*, and Qi-Lin Zhou*,Development of Chiral Spiro P-N-S Ligands for Iridium-Catalyzed Asymmetric Hydrogenation of b-Alkyl-b-Ketoesters. Angew. Chem. Int. Ed. 2015, 54, 8791-8794.

132. Na Guo, Meng-Yang Hu, Ye Feng, Shou-Fei Zhu*, Highly efficient and practical hydrogenation of olefins catalyzed by in situ generated iron complex catalysts, Org. Chem. Front. 2015, 2, 692 - 696

131. Na Guo, Shou-Fei Zhu*, Iron-catalyzed hydrogenation reactions (铁催化氢化反应研究进展), Chin. J. Org. Chem. 2015, 35, 1383-1398.

130. Qing-Qing Cheng, Huan Xu, Shou-Fei Zhu*, Qi-Lin Zhou, Enantioselective copper-catalyzed B‒H bond insertion reaction of α-diazoketones (铜催化α-重氮酮对硼氢键的不对称插入反应), Acta Chim. Sinica. 2015, 73(4), 326-329. (Cover Story)

129. Jing Hou, Jian-Hua Xie, and Qi-Lin Zhou*. Palladium-Catalyzed Hydrocarboxylation of Alkynes with Formic Acid. Angew. Chem. Int. Ed. 2015, 54. 6302-6305.

128. Chong Liu, Jian-Hua Xie, Gui-Long Tian, Wei Li and Qi-Lin Zhou*.Highly eﬃcient hydrogenation of carbon dioxide to formate catalyzed by iridium(III ) complexes of imine–diphosphine ligands.Chem. Sci.,2015, 6, 2928-2931

127. Wei-Peng Liu, Ming-Lei Yuan, Xiao-Hui Yang, Ke, Li, Jian-Hua Xie*, Qi-Lin Zhou*.Efficient Asymmetric Transfer Hydrogenation of Ketones in Ethanol with Chiral Iridium Complexes of SpiroPAP Ligands as Catalysts.Chem.Commun., 2015, 5, 6123-6125

126. Cui Guo, Dong-Wei Sun, Shuang Yang, Shen-Jie Mao, Xiao-Hua Xu^*, Shou-Fei Zhu^*, and Qi-Lin Zhou^*, Iridium-catalyzed asymmetric hydrogenation of 2-pyridyl cyclic imines: a highly enantioselective approach to nicotine derivatives, J. Am. Chem. Soc. 2015, 137, 90-93.

125. Jian-Hua Xie*, Deng-Hui Bao, Qi-Lin Zhou, Recent Advances in the Development of Chiral Metal Catalysts for the Asymmetric Hydrogenation of Ketones.Synthesis, 2015; 47(04):460-471

124. Xiao-Hui Yang, Ke Wang, Shou-Fei Zhu, Jian-Hua Xie*, and Qi-Lin Zhou*.Remote Ester Group Leads to Efficient Kinetic Resolution of Racemic Aliphatic Alcohols via Asymmetric Hydrogenation.J. Am. Chem. Soc., 2014, 136 (50), pp 17426–17429.

123. Shou-Fei Zhu*, and Qi-Lin Zhou*, Iron-catalyzed transformations of dizao compounds, National Science Review 2014, DOI: 10.1093/nsr/nwu019.

122. Ze-Yu Li, Song Song, Shou-Fei Zhu*, Na Guo, Li-Xin Wang, and Qi-Lin Zhou*, Synthesis of chiral α-benzyl-β2-hydroxy carboxylic acids through iridium-catalyzed asymmetric hydrogenation of α-oxymethylcinnamic acids, Chin. J. Chem. 2014, 32, 783-787.

121.Jun-Jie Shen, Shou-Fei Zhu*, Yan Cai, Huan Xu, Xiu-Lan Xie, and Qi-Lin Zhou, Enantioselective iron-catalyzed intramolecular cyclopropanation reactions, Angew. Chem. Int. Ed. 2014, 53,13188-13191 (Highlighted by Synfacts 2014, 10, 1284).

120. Ming-Lei Yuan, Jian-Hua Xie*, Xiao-Hui Yang, Qi-Lin Zhou*,Enantioselective Synthesis of Chiral 1,2-Amino Alcohols via Asymmetric Hydrogenation of α-Amino Ketones with Chiral Spiro Iridium Catalysts, Synthesis 2014; 46(21): 2910-2916.

119. Jian-Hua Xie*, Qi-Lin Zhou*, Magical chiral spiro ligands, Acta Chim. Sinica, 2014, 72, 778-797

神奇的手性螺环配体

118. Wei Li, Jian-Hua Xie, Ming-Lei Yuana and Qi-Lin Zhou*, Ruthenium complexes of tetradentate bipyridine ligands: highly efficient catalysts for the hydrogenation of carboxylic esters and lactones, Green Chem., 2014,16, 4081-4085

117. Shuang Yang, Shou-Fei Zhu, Na Guo, Song Song and Qi-Lin Zhou*, Carboxy-directed asymmetric hydrogenation of α-alkyl-α-aryl terminal olefins: highly enantioselective and chemoselective access to a chiral benzylmethyl center, Org. Biomol. Chem. 2014, 12, 2049-2052

116. Bin Xu, Shou-Fei Zhu*, Xiao-Dong Zuo, Zhi-Chao Zhang, Qi-Lin Zhou*, Enantioselective N-H Insertion Reaction of α-Aryl α-Diazoketones: An Efficient Route to Chiral α-Aminoketones, Angew. Chem. Int. Ed. 2014, 53,3913-3916

115. Xiu-Lan Xie, Shou-Fei Zhu*, Jun-Xia Guo, Yan Cai, Qi-Lin Zhou*, Enantioselective Palladium-Catalyzed Insertion of α-Aryl-α-diazoacetates into the O-H Bonds of Phenols, Angew. Chem. Int. Ed. 2014, 53, 2978-2981.

114. Xiao-Hui Yang, Jian-Hua Xie*, Qi-Lin Zhou*, Chiral spiro iridium catalysts with SpiroPAP ligands: highly efficient for asymmetric hydrogenation of ketones and ketoesters, Org. Chem. Front. 2014, 1, 190-193.

113. Bin Xu, Shou-Fei Zhu*, Zhi-Chao Zhang, Zhi-Xiang Yu*, Yi Ma, Qi-Lin Zhou*, Highly enantioselective S–H bond insertion cooperatively catalyzed by dirhodium complexes and chiral spiro phosphoric acids, Chem. Sci. 2014, 5, 1442-1448.

112. Qing-Qing Cheng, Shou-Fei Zhu*, Yong-Zhen Zhang, Xiu-Lan Xie, and Qi-Lin Zhou*, Copper-Catalyzed B–H Bond Insertion Reaction: A Highly Efficient and Enantioselective C–B Bond-Forming Reaction with Amine- and Phosphine-Borane Adducts, J. Am. Chem. Soc., 2013,135, 14094-14097

111. Song Song, Shou-Fei Zhu, Yu Li, and Qi-Lin Zhou*, Iridium-Catalyzed Enantioselective Hydrogenation of α,β-Unsaturated Carboxylic Acids with Tetrasubstituted Olefins, Org. Lett., 2013, 15, 3722-3725

110. Xiao-Hui Yang, Jian-Hua Xie*, Wei-Peng Liu, Qi-Lin Zhou*,Catalytic Asymmetric Hydrogenation of δ-Ketoesters: Highly Efficient Approach to Chiral 1,5-Diols, Angew. Chem. Int. Ed. 2013, 52, 7833-7836.

109. Gang Li, Jian-Hua Xie*, Jing Hou, Shou-Fei Zhu, Qi-Lin Zhou*, Catalytic Asymmetric Hydrogenation of α-Arylcyclohexanones and Total Synthesis of (−)-α-Lycorane, Adv. Synth. Catal. 2013, 355, 1597–1604

108. Dr. Song Song,Shou-Fei Zhu, Liu-Yang Pu, Qi-Lin Zhou*, Iridium-Catalyzed Enantioselective Hydrogenation of Unsaturated Heterocyclic Acids, Angew. Chem. Int. Ed. 2013, 52, 6072-6075.

107(b). Bo Zhang, Shou-Fei Zhu*, Qi-Lin Zhou*, Copper-catalyzed enantioselective allylic oxidation of acyclic olefins, Tetrahedron Lett. 2013, 54, 2665–2668.

107(a). Bo Zhang, Shou-Fei Zhu*, and Qi-Lin Zhou*,Copper-catalyzed benzylic oxidation of C(sp3)-H bonds, Tetrahedron. 2013, 69, 2033-2037.

106. Li-Jie Cheng, Jian-Hua Xie*, Yong Chen, Li-Xin Wang, Qi-Lin Zhou*, Enantioselective Total Synthesis of (-)-Δ⁸-THC and (-)-Δ⁹-THC via Catalytic Asymmetric Hydrogenation and SNAr Cyclization, Org. Lett. 2013, 15, 764-767.

105. Chong Liu, Jian-Hua Xie*, Ya-Li Li, Ji-Qiang Chen, Qi-Lin Zhou*, Asymmetric Hydrogenation of a,a'-Disubstituted Cycloketones via Dynamic Kinetic Resolution: An Efficient Construction of Chiral Diols with Three Contiguous Stereocenters, Angew. Chem. Int. Ed., 2013, 52,593–596.

104. Xiao-Guang Song, Shou-Fei Zhu, Xiu-Lan Xie, and Qi-Lin Zhou*, Highly Enantioselective Copper-Catalyzed Intramolecular Phenolic O‒H Bond Insertion: An Efficient Synthesis of Chiral 2-Carboxy Dihydro-benzofurans, Dihydrobenzopyrans and Tetrahydrobenzooxepines**, Angew. Chem. Int. Ed. 2013, 52, 2555-2558.

103. Jian-Hua Xie*, Qi-Lin Zhou*, New progress and prospects of transition metal-catalyzed asymmetric hydrogenation. Acta Chim. Sinica 2012, 70(13), 1427-1438.

102. Dr. Song Song, Shou-Fei Zhu, Yan-Bo Yu, Qi-Lin Zhou*, Carboxy-Directed Asymmetric Hydrogenation of 1,1-Diarylethenes and 1,1-Dialkylethenes, Angew. Chem. Int. Ed. 2013, 52, 1556-1559.

101. Qian-Qian Zhang, Jian-Hua Xie*, Xiao-Hui Yang, Jian-Bo Xie, Qi-Lin Zhou*, Iridium-Catalyzed Asymmetric Hydrogenation of a-Substituted α,b-Unsaturated Acyclic Ketones: Enantioselective Total Synthesis of (-)-Mesembrine, Org. Lett., 2012, 14, 6158–6161

100. Jian-Hua Xie*, Lu-Chuan Guo, Xiao-Hui Yang, Li-Xin Wang, Qi-Lin Zhou*, Enantioselective Synthesis of 2,6-cis-Disubstituted Tetrahydropyrans via a Tandem Catalytic Asymmetric Hydrogenation/Oxa-Michael Cyclization: An Efficient Approach to (-)-Centrolobine, Org. Lett., 2012, 14 ,4758–4761

99. Wei Li, Jian-Hua Xie, Han Lin and Qi-Lin Zhou*, Highly Efficient Hydrogenation of Biomass-derived Levulinic Acid to g-Valerolactone Catalyzed by Iridium Pincer Complexes,Green Chem., 2012,14, 2388-2390

98. Shou-Fei Zhu, Yan-Bo Yu, Shen Li, Li-Xin Wang, and Qi-Lin Zhou*, Enantioselective Hydrogenation of a-Substituted Acrylic Acids Catalyzed by Iridium Complexes with Chiral Spiro Aminophosphine Ligands, Angew. Chem. Int. Ed. 2012, 51, 8872–8875

97. Shuang Yang, Shou-Fei Zhu, Can-Ming Zhang, Song Song, Yan-Bo Yu, Shen Li, Qi-Lin Zhou*,Enantioselective iridium-catalyzed hydrogenation of α-arylcinnamic acids and synthesis of (S)-equol, Tetrahedron 2012, 68, 5172-5178

96. Shou-Fei Zhu, Qi-Lin Zhou*, Transition-metal-catalyzed enantioselective heteroatom–hydrogen bond insertion reactions, Acc. Chem. Res. 2012, 45, 1365-1377

95. Li-Jie Cheng, Jian-Hua Xie*, Li-Xin Wang, Qi-Lin Zhou*, Enantioselective Synthesis of (-)-CP-55940 via Ruthenium-Catalyzed Asymmetric Hydrogenation of Ketone, Adv. Synth. Catal. 2012, 354, 1105 – 1113

94. Ji-Qiang Chen, Jian-Hua Xie*, Deng-Hui Bao, Sheng Liu, and Qi-Lin Zhou*, Total Synthesis of (−)-Galanthamine and (−)-Lycoramine via Catalytic Asymmetric Hydrogenation and Intramolecular Reductive Heck Cyclization, Org. Lett., 2012, 14, 2714–2717

93. Jian-Hua Xie,* Shou-Fei Zhu and Qi-Lin Zhou*, Recent advances in transition metal-catalyzed enantioselective hydrogenation of unprotected enamines, Chem. Soc. Rev., 2012, 41, 4126–4139

92. Jian-Hua Xie, Pu-Cha Yan, Qian-Qian Zhang, Ke-Xing Yuan, and Qi-Lin Zhou* Asymmetric Hydrogenation of Cyclic Imines Catalyzed by Chiral Spiro Iridium- Phosphoramidite Complexes for Enantioselective Synthesis of Tetrahydroisoquinolines, ACS Catal. 2012, 2, 561−564

91. Song Song,Prof. Shou-Fei Zhu,Shuang Yang,Shen Li,Prof. Qi-LinZhou^*Enantioselective Iridium-Catalyzed Hydrogenation of β,γ-Unsaturated Carboxylic Acids: An Efficient Approach to Chiral 4-Alkyl-4-aryl Butanoic Acids, Angew. Chem. Int. Ed. 2012, 51, 2708–2711

90. Shou-Fei Zhu, Bin Xu, Guo-Peng Wang, and Qi-Lin Zhou*, Well-Defined Binuclear Chiral Spiro Copper Catalysts for Enantioselective N-H Insertion, J. Am. Chem. Soc. 2012, 134, 436–442

89. Jian-Hua Xie,* Xiao-Yan Liu, Xiao-Hui Yang, Jian-Bo Xie, Li-Xin Wang, and Qi-Lin Zhou*, Chiral Iridium Catalysts Bearing Spiro Pyridine-Aminophosphine Ligands Enable Highly Efficient Asymmetric Hydrogenation of b-Aryl b-Ketoesters, Angew. Chem. Int. Ed. 2012, 51, 201 –203

88. Qiu-Shi Wang, Jian-Hua Xie, Lu-Chuan Guo and Qi-Lin Zhou*, Synthesis of a,b-unsaturated c-amino esters with a quaternary center by ruthenium-catalyzed codimerization of N-acetyl a-arylenamines and acrylates. Org. Biomol. Chem., 2012, 10, 43–45

87. Jian-Bo Xie, Jian-Hua Xie*, Xiao-Yan Liu, Qian-Qian Zhang, Qi-Lin Zhou*, Chiral iridium spiro aminophosphine complexes: asymmetric hydrogenation of simple ketones, structure and plausible mechanism, Chem. Asian J. 2011, 6, 899-908.

86. Yan Cai, Shou-Fei Zhu, Guo-Peng Wang and Qi-Lin Zhou*, Iron-Catalyzed C-H Fuctionalization of Indoles, Adv. Synth. Catal. 2011, 353, 2939–2944

85. Shou-Fei Zhu, Wang-Qiao Chen, Qian-Qian Zhang, Hong-Xiang Mao, Qi-Lin Zhou*. Enantioselective Copper-Catalyzed O–H Insertion of a-Diazo Phosphonates, SYNLETT 2011,7, 0919–0922

84. Bin Xu, Shou-Fei Zhu,* Xiu-Lan Xie, Jun-Jie Shen, and Qi-Lin Zhou*, Asymmetric N-H Insertion Reaction Cooperat-ively Catalyzed by Rhodium and Chiral Spiro Phosphoric Acids, Angew. Chem. Int . Ed. 2011, 50 , 11483 –11486

83. Qiu-Shi Wang, Jian-Hua Xie, Wei Li, Shou-Fei Zhu, Li-Xin Wang, and Qi-Lin Zhou*, Ruthenium-Catalyzed Hydro-vinylation of N-Acetylenamines Leading to Amines with a Quaternary Carbon Center, Org. Lett., 2011, 13, 3388– 3391.

82. Jian-Hua Xie*, Xiao-Yan Liu, Jian-Bo Xie, Li-Xin Wang, and Qi-Lin Zhou*, An Additional Coordination Group Leads to Extremely Efficient Chiral Iridium Catalysts for Asymmetric Hydrogenation of Ketones, Angew. Chem. Int. Ed, 2011, 50, 7329–7332.

81. Shou-Fei Zhu, Xiang-Chen Qiao, Yong- Zhen Zhang, Li-Xin Wang and Qi-Lin Zhou*, Highly enantioselective palladium-catalyzed umpolung allylation of aldehydes, Chem. Sci., 2011, 2, 1135–1140.

80. Jian-Hua Xie, Shou-Fei Zhu, Qi-Lin Zhou*, Transition metal-catalyzed enantioselective hydrogenation of enamines and imine,Chem. Rev., 2011, 111, 1713–1760.

79. Shou-Fei Zhu, Xiao-Guang Song, Yu Li, Yan Cai, and Qi-Lin Zhou *, Enantioselective Copper-Catalyzed Intramolecular O−H Insertion: An Efficient Approach to Chiral 2-Carboxy Cyclic Ethers , J. Am. Chem. Soc. 2010, 132,16374–16376.

78. Wen-Ju Bai, Jian-Hua Xie, Ya-Li Li, Sheng Liu, Qi-Lin Zhou*, Enantioselective synthesis of chiral β-aryloxyalcohols by ruthenium- catalyzed ketone hydrogenation via DKR, Adv. Synth. Catal. 2010, 352, 81-84.

77. Pu-Cha Yan, Jian-hua Xie, Qi-Lin Zhou*, Asymmetric hydrogenation of unfunctionalized enamines catalyzed by iridium complexes of chiral spiro N,N-diarylphosphoramidites, Chinese J. Chem. 2010, 28, 1736-1742.

76. Qi Zhang, Shou-Fei Zhu, Yan Cai, Li- Xin Wang, Qi-Lin Zhou*, Nickel-catalyzed enantioselective hydrovinylation of silyl- protected allylic alcohols: an efficient access to homoallylic alcohols with α chiral quaternary center, Science China Chemistry 2010, 53, 1899-1906.

75. Chang-Yue Zhou, Shou-Fei Zhu, Li-Xin Wang, and Qi-Lin Zhou*, Enantioselective nickel-catalyzed reductive coupling of alkynes and imines, J. Am. Chem. Soc. 2010, 132, 10955-10957.

74. Shou-Fei Zhu, Yan Cai, Hong-Xiang Mao, Jian-Hua Xie, and Qi-Lin Zhou*, Enantioselective Iron-Catalyzed O–H Βond Insertions,Nature Chemistry, 2010, 2, 546−551.

73. Xiang-Chen Qiao, Shou-Fei Zhu, Wang- Qiao Chen, and Qi-Lin Zhou*, Palladium-catalyzed asymmetric umpolung allylation of imines with allylic alcohols, Tetrahedron: Asymmetry 2010, 21, 1216-1220.

72. Jian-Βo Xie, Jian-Hua Xie*, Xiao-Yan Liu, Wei-Ling Kong, Shen Li, and Qi-Lin Zhou*, Highly enantioselective hydrogenation of α-arylmethylene cycloalkanones catalyzed by iridium complexes of chiral spiro aminophosphine ligands, J. Am. Chem. Soc. 2010, 132, 4538- 4539.

71. Shen Li, Shou-Fei Zhu, Jian-Hua Xie, Song Song, Can-Ming Zhang, and Qi-Lin Zhou*, Enantioselective hydrogenation of α-aryloxy and α-alkoxy α,β-unsaturated carboxylic acids catalyzed by chiral spiro iridium/phosphino-oxazoline complexes, J. Am. Chem. Soc. 2010, 132, 1172- 1179.

70. Pu-Cha Yan, Jian-Hua Xie, Guo-Hua Hou, Li-Xin Wang, Qi-Lin Zhou*, Enantioselective synthesis of chiral tetrahydroisoquinolines by iridium-catalyzed asymmetric hydrogenation of enamines, Adv. Synth. Catal. 2009, 351, 3243-3250.

69. Zhang-Tao Zhou, Jian-Hua Xie, Qi-Lin Zhou*, Enantioselective synthesis of chiral β-aryloxy alcohols by asymmetric hydrogenation of β-aryloxy aldehydes via dynamic kinetic resolution, Adv. Synth. Catal. 2009, 351, 363-366.

68. Sheng Liu, Jian-Hua Xie, Wei Li, Wei- Ling Kong, Li-Xin Wang, Qi-Lin Zhou*, Highly enantioselective synthesis of chiral cyclic amino alcohols and conhydrine by ruthenium-catalyzed asymmetric hydrogenation, Org. Lett. 2009, 11, 4994-4997.

67. Xiang-Chen Qiao, Shou-Fei Zhu, Qi-Lin Zhou*, From allylic alcohols to chiral tertiary homoallylic alcohol: palladium-catalyzed asymmetric allylation of isatins, Tetrahedron: Asymmetry 2009, 20, 1254-1261.

66. Jian-Hua Xie, Wei-Ling Kong, Xiao-Cheng Wang, Wen-Ju Bai, Li-Xin Wang, Qi-Lin Zhou*, Chiral ruthenium-SDPs/diamine complexes-catalyzed enantioselective hydrogenation of α-alkyl arylacetones via dynamic kinetic resolution, Front. Chem. China 2009, 4, 299-306.

65. Yong-Zhen Zhang, Shou-Fei Zhu, Yan Cai, Hong-Xiang Mao, Qi-Lin Zhou*, Copper-catalyzed enantioselective carbenoid insertion into S–H bonds, Chem. Commun. 2009, 5362-5364.

64. Jian-Hua Xie, Sheng Liu, Wei-Ling Kong, Wen-Jun Bai, Xiao-Chen Wang, Li-Xin Wang, Qi-Lin Zhou*, Highly enantioselective and diastereoslective synthesis of chiral amino alcohols by ruthenium- catalyzed asymmetric hydrogenation of α-amino aliphatic ketones, J. Am. Chem. Soc. 2009, 131, 4222-4223.

63. Guo-Hua Hou, Jian-Hua Xie, Pu-Cha Yan, Qi-Lin Zhou*, Iridium-catalyzed asymmetric hydrogenation of cyclic enamines, J. Am. Chem. Soc. 2009, 131, 1366- 1367.

62. Jian-Hua Xie, Qi-Lin Zhou*, Chiral diphosphine and monodentate phosphorus ligands on α spiro scaffold for transition-metal-catalyzed asymmetric reactions Acc. Chem. Res. 2008, 41, 581-593.

61. Yun Yang, Shou-Fei Zhu, Chang-Yue Zhou, Qi-Lin Zhou*, Nickel-catalyzed enantioselective alkylative coupling of alkynes and aldehydes: synthesis of chiral allylic alcohols with tetrasubstituted olefins, J. Am. Chem. Soc. 2008, 130, 14052-14053.

60. Shen Li, Shou-Fei Zhu, Can-Ming Zhang, Song Song, Qi-Lin Zhou*, Iridium-catalyzed enantioselective hydrogenation of α,β-unsaturated carboxylic acids,J. Am. Chem. Soc. 2008, 130, 8584-8585.

59. Hai-Feng Duan, Jian-Hua Xie, Xiang- Chen Qiao, Li-Xin Wang, Qi-Lin Zhou*, Enantioselective rhodium-catalyzed addition of arylboronic acids to α-ketoesters, Angew. Chem. Int. Ed. 2008, 47, 4351-4353.

58. Yong-Zhen Zhang, Shou-Fei Zhu, Li-Xin Wang, Qi-Lin Zhou*, Copper-catalyzed highly enantioselective carbenoid insertion into Si–H Βonds, Angew. Chem. Int. Ed. 2008, 47, 8496-8498.

57. Shou-Fei Zhu, Chao Chen, Yan Cai, Qi- Lin Zhou*, Catalytic asymmetric reaction with water: Enantioselective synthesis of α-hydroxyesters by copper-carbenoid O–H insertion reaction, Angew. Chem. Int. Ed. 2008, 47, 932-934.

56. Liang Xing, Jian-Hua Xie, Yong-Sheng Chen, Li-Xin Wang, Qi-Lin Zhou*, Simply modified chiral diphosphine: catalyst recycling via non-covalent absorption on carbon nanotubes, Adv. Synth. Catal. 2008, 350, 1013-1016.

55. Qi Zhang, Shou-Fei Zhu, Xiang-Chen Qiao, Li-Xin Wang, Qi-Lin Zhou*, Nickel-catalyzed highly selective hydrovinylation of α-ketals of vinylarenes, Adv. Synth. Catal. 2008, 350, 1507-1510.

54. Wei Zhang, Shou-Fei Zhu, Xiang-Chen Qiao, Qi-Lin Zhou*, Highly enantioselective copper-catalyzed ring opening of oxabicyclic alkenes with Grignard reagents, Chem. Asian J. 2008, 3, 2105-2111.

53. Xiang-Hong Huo, Jian-Hua Xie, Qiu-Shi Wang, and Qi-Lin Zhou, The Synthesis of Spirobitetraline Phosphoramidite Ligands and their Application in Rhodium-Catalyzed Asymmetric Hydrogenation, Adv.Synth. Catal. 2007, 349, 2477-2484.

52. Chao Chen, Shou-Fei Zhu, Βin Liu, Li- Xin Wang, Qi-Lin Zhou*, Highly enantioselective insertion of carbenoids into O–H bonds of phenols: An efficient approach to chiral α-aryloxycarboxylic esters, J. Am. Chem. Soc. 2007, 129, 12616-12617.

51. Bin Liu, Shou-Fei Zhu, Wei Zhang, Chao Chen, Qi-Lin Zhou*, Highly enantioselective insertion of carbenoids into N-H bonds catalyzed by copper complexes of chiral spiro bisoxazolines, J. Am. Chem. Soc. 2007, 129, 5834-5835.

50. Yun Yang, Shou-Fei Zhu, Hai-Feng Duan, Chang-Yue Zhou, Li-Xin Wang, Qi-Lin Zhou*, Asymmetric reductive coupling of dienes and aldehydes catalyzed by nickel complexes of spiro phosphoramidites: Highly enantioselective synthesis of chiral bishomoallylic alcohols, J. Am. Chem. Soc. 2007, 129, 2248- 2249.

49. Jian-Hua Xie, Zhang-Tao Zhou, Wei-Ling Kong, Qi-Lin Zhou*, Ru-Catalyzed asymmetric hydrogenation of racemic aldehydes via dynamic kinetic resolution: efficient synthesis of optically active primary alcohols, J. Am. Chem. Soc. 2007, 129, 1868-1869.

48. Bao-Min Fan, Jian-Hua Xie, Shen Li, Li-Xin Wang, Qi-Lin Zhou*, Highly enantioselective silylcarbocyclization of 1,6-enynes catalyzed by Rh(I)-SDP complexes, Angew. Chem. Int. Ed. 2007, 46, 1275-1277.

47. Yi-Xia Jia, Jun Zhong, Shou-Fei Zhu, Can-Ming Zhang, Qi-Lin Zhou*, Chiral Βrønsted acid catalyzed enantioselective Friedel-Crafts reaction of indoles and α-aryl enamides: construction of chiral quaternary carbons, Angew. Chem. Int. Ed. 2007, 46, 5565-5567.

46. Sheng Liu, Jian-Hua Xie, Li-Xin Wang, Qi-Lin Zhou*, Dynamic kinetic resolution allows α highly enantioselective synthesis of cis--aminocycloalkanols by ruthenium-catalyzed asymmetric hydrogenation, Angew. Chem. Int. Ed. 2007, 46, 7506-7508.

45. Liang Xing, Feng Du, Jia-Jie Liang, Yong-Sheng Chen*, Qi-Lin Zhou*, Preparation of Pt/SWNTs for heterogeneous asymmetric hydrogenation of ethyl pyruvate, J. Mol. Catal. Α: Chem. 2007, 276, 191-196.

44. Wen-Jian Shi, Qi Zhang, Jian-Hua Xie, Shou-Fei Zhu, Guo-Hua Hou, Qi-Lin Zhou*, Highly enantioselective hydrovinylation of α-alkyl vinylarenes. An approach to the construction of all-carbon quaternary stereocenters, J. Am. Chem. Soc. 2006, 128, 2780-2781.

43. Guo-Hua Hou, Jian-Hua Xie, Lin-Xin Wang, Qi-Lin Zhou*, Highly efficient Rh(I)-catalyzed hydrogenation of enamines using monodentate spiro phosphonite ligands, J. Am. Chem. Soc. 2006, 128, 11774-11775.

42. Shou-Fei Zhu, Jian-Βo Xie, Yong-Zhen Zhang, Shen Li, Qi-Lin Zhou*, Well-defined chiral spiro Ir/phosphine-oxazoline cationic complexes for highly enantioselective hydrogenation of imines at ambient pressure,J. Am. Chem. Soc. 2006, 128, 12886-12891.

41. Xu Cheng, Jian-Hua Xie, Sheng Li, Qi- Lin Zhou*, Ru(II)-SFDP complexes catalyzed asymmetric hydrogenation of α,β-unsaturated carboxylic acids, Adv. Synth. Catal. 2006, 348, 1271-1276.

40. Hai-Feng Duan, Jian-Hua Xie, Wen-Jian Shi, Qi Zhang, Qi-Lin Zhou*, Enantioselective rhodium-catalyzed addition of arylboronic acids to aldehydes using chiral spiro monophosphite ligands, Org. Lett. 2006, 8, 1479-1481.

39. Yi-Xia Jia, Jian-Hua Xie, Hai-Feng Duan, Li-Xin Wang, Qi-Lin Zhou*, Asymmetric Friedel–Crafts addition of indoles to N-sulfonyl aldimines: Α simple approach to optically active 3- indolylmethanamine derivatives, Org. Lett. 2006, 8, 1621-1624.

38. Hai-Feng Duan, Yi-Xia Jia, Li-Xin Wang, Qi-Lin Zhou*, Enantioselecitive Rh-catalyzed arylation of N-tosylarylimines with arylboronic acids,Org. Lett. 2006, 8, 2567-2569.

37. Yi-Xia Jia, Shuo-Fei Zhu, Yun Yang, Qi-Lin Zhou*, Asymmetric Friedel–Crafts alkylations of indoles with nitroalkenes catalyzed by Zn(II)-bisoxazoline complexes, J. Org. Chem. 2006, 71, 75-80.