PAPER-906-14-I-1969

A SIMPLE@ ACCURATE@ FAST METHOD FOR CALCULATING CALCIUM SULFATE SOLUBILITY IN OIL FIELD BRINE


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标准号
PAPER-906-14-I-1969
发布日期
1969年03月14日
实施日期
2011年03月23日
废止日期
中国标准分类号
/
国际标准分类号
/
发布单位
API - American Petroleum Institute
引用标准
21
适用范围
INTRODUCTION Until 1966 the method of Stiff and Davis(1) for predicting the tendency of oil field water to deposit calcium sulfate was used extensively by Atlantic. Richfield Co. This predictive method correlates well with field observations in brines of low ionic strength or those composed primarily of sodium chloride. However@ in the case of brines containing excessive common ion and/or magnesium@ the correlation diminishes as the concentration of these ions increases. This has been recognized by Atlantic Richfield and various individuals using the Stiff and Davis predictive method. (2@ 3@ 4) Therefore@ a more exact@ yet simple@ predictive technique was sought. Since 1966 Atlantic Richfield has calculated calcium sulfate solubility in brine by the classical thermodynamic method using available solubility data from the literature. More recently@ these calculations have been made using solubility data produced in this laboratory. These measurements were made under carefully controlled conditions specifically to provide solubility product constants throughout the range of temperature and ionic strength common in oil field operations. To simplify calculations@ a program has been written utilizing time sharing computer service.




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