prEN ISO 6923
油漆和清漆 使用高效液相色谱和紫外检测器 (HPLC-UV) 测定涂料和类似产品中的单体二异氰酸酯含量 (ISO 6923:2023)

Paints and varnishes - Determination of monomeric diisocyanate content in coating materials and similar products using high performance liquid chromatography with ultraviolet detection (HPLC-UV) (ISO 6923:2023)


 

 

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标准号
prEN ISO 6923
发布单位
欧洲标准化委员会
 
 
适用范围
This document specifies a method for the quantitative determination of monomeric diisocyanate content in coating materials, adhesives and other liquid or pasty materials. This method is suitable for the quantification of the following monomeric diisocyanates: methylene diphenyl diisocyanate (MDI, 2,4’-MDI and 4,4’-MDI), toluene diisocyanate (TDI, 2,6-TDI, 2,4-TDI), (cis/trans) isophorone diisocyanate (IPDI) and hexamethylene diisocyanate (HDI,1,6-HDI) in various matrices for concentrations ranging from 0,01 % to 2,0 % mass fraction. For higher concentrations, a suitable dilution before the derivatization with p-nitrobenzyl-N-propylamine (PNBPA) is performed. The measurements are carried out using ultra high performance liquid chromatography (UHPLC) with a multiple wavelength detector.

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