This document specifies a method for the chromatographic determination of the iron chelated by each individual ortho(hydroxy)-ortho(hydroxy) isomer of the chelating agents o,o-EDDHA and o,oEDDHMA in fertilizers containing one or both of these substances. The method allows the identification and the determination of the total concentration of water soluble iron chelates of these chelating agents.lt does not determine the free form of the chelating agents. NOTE 1 The substances EDDHA(ethylene diamine di(hydroxy phenyl) acetic acid)and EDDHMA(ethylene diaminedi(hydroxy methyl phenyl)acetic acid) exist as several different isomeric forms. Positional isomers for the hydroxyl ormethyl groups(in ortho,meta,and para positions)as well as stereo isomers(meso and dl-racemic forms)are known.Bothmeso and dl-racemic forms of the ortho,ortho-EDDHA andortho,ortho-EDDHMA are positional isomers for the hydroxyl groups allowed by the Regulation(EC) No 2003/2003. Since para,method here described the para,meta and ortho methyl positional isomers of the o,o-EDDHMA are considered together. NOTE 2 At present,analyticallypure standards only exist for ortho,ortho-EDDHA and ortho,ortho-EDDHAM.All other substances being unavailable as a standard,the influence of their eventual presence in the samples(with respect to the sensitivity and the selectivity of this method)has not been studied. NOTE 3 The meso and the dl-racemic forms of o,o-EDDHA and o,o-EDDHMA can be determined separately by this method. This procedure concerns EC fertilizers covered by Regulation (EC)No 2003/2003[5].lt is applicable to a mass fraction of the metal chelated of at least 0,625﹪.
DIN EN 13368-2-2007由德国标准化学会 DE-DIN 发布于 2007-06。
DIN EN 13368-2-2007 在中国标准分类中归属于: B10 土壤、肥料综合,在国际标准分类中归属于: 65.080 肥料。
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