ISO 15680-2003 水质.用purge-and-trap和热解析作用对单环芳香烃、萘和不同氯化物的气相色谱分析测定
Water quality - Gas-chromatographic determination of a number of monocyclic aromatic hydrocarbons, naphthalene and several chlorinated compounds using purge-and-trap and thermal desorption
This International Standard specifies a general method for the determination of volatile organic compounds (VOCs) in water by purge-and-trap isolation and gas chromatography (GC). Annexes A, B and C provide examples of analytes that can be determined using this International Standard. They range from difluorodichloromethane (R-12) up to trichlorobenzene, including all non-polar organic compounds of intermediate volatility.
Detection is preferably carried out by mass spectrometry in the electron impact mode (El), but other detectors may be applied as well.
The limit of detection largely depends on the detector in use and the operational parameters. Typically detection limits as low as 10 ng/l can be achieved. The working range typically is up to 100 μg/l.
This International Standard is applicable to drinking water, ground water, surface water, seawater and to (diluted) waste water.
note: 1) The value given is an indication of the limit of detection. It is calculated as 3 times the standard deviation of a series of measurements of 10 replicate samples under conditions of repeatability.