83015 A-2005

Thermal conductivity of liquids: Heterocyclic nitrogen compounds.


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标准号
83015 A-2005
发布日期
2005年09月01日
实施日期
2006年06月27日
废止日期
中国标准分类号
/
国际标准分类号
/
发布单位
ESDU - Engineering Sciences Data Unit
引用标准
46
适用范围
ESDU 83015 contains liquid thermal conductivity data for sixteen alkyl and alkenyl pyridines@ ten alkyl quinolines@ three alkyl pyrroles@ pyrrolidine and piperidine. Experimental results drawn from the literature for each pure compound were fitted with a four-term polynomial equation in reduced temperature. The coefficients were also faired with changing molecular structure to ensure the best correlation not only for the individual compounds but also for them as members of their chemical series. The coefficient correlations also allowed values to be predicted for those pure compounds for which no measured data exist. The equations were used to tabulate thermal conductivity values at saturation pressure@ from the melting temperature where known or an appropriate starting point@ to about 0.9 of the critical temperature in SI units at 10 K and 10 degree Celsius intervals. The likely uncertainties in the values presented are indicated in the text. The critical temperature@ coefficients and sources of the data are given for each compound. An approximate expression@ valid between the melting and boiling temperatures is given for the effect of pressure up to 50 MPa.




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