Separation and identification of stabilizers used in the manufacture of polypropylene is necessary in order to correlate performance properties with polymer composition. This test method provides a means to determine erucamide slip, Vitamin E, Irgafos 168, Irganox 3114, Irganox 1010, and Irganox 1076 levels in polypropylene samples. This test method is also applicable for the determination of other antioxidants, such as Ultranox 626, Ethanox 330, Santanox R, and BHT, but the applicability of this test method has not been investigated for these antioxidants.
The additive-extraction procedure is made effective by the insolubility of the polymer sample in solvents generally used for liquid chromatographic analysis.
Under optimum conditions, the lowest level of detection for a phenolic antioxidant is approximately 2 ppm.
Note 28212;Other methods that have been used successfully to remove additives from the plastics matrix include thin film, microwave, ultrasonic, and supercritical fluid extractions. Other methods have been used successfully to separate additives including SFC and capillary GC.
Irgafos 168 is a phosphite antioxidant. Phosphites are known to undergo both oxidation and hydrolysis reactions. Less Irgafos 168 will be determined in the polymer when oxidation occurs during processing. The HPLC separation is capable of separating the phosphite, phosphate (oxidation product), and hydrolysis product and quantify them if standards are obtained. No significant breakdown of the phosphite antioxidant has been seen due to either extraction technique or the separation presented in this standard.
1.1 This test method covers a liquid-chromatographic procedure for the separation of some additives currently used in polypropylene. These additives are extracted with a cyclohexane:methylene chloride mixture using either reflux or ultrasonic bath prior to liquid-chromatographic separation. The ultraviolet absorbance (200 nm) of the compound(s) is measured, and quantitation is performed using the internal standard method.
1.2 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use. Specific precautionary statements are given in Section 9. Note 18212;There is no known ISO equivalent to this test method.
其中,十种工程塑料包括:聚酰胺、聚碳酸酯、聚甲醛、聚对苯二甲酸丁二醇酯、聚苯醚、聚苯硫醚、聚砜、聚酰亚胺、聚醚醚酮和液晶聚合物。5、塑料基本性能与工程塑料主要特性发展对比文章提纲式、分点对比介绍塑料基本性能、工程塑料具有的性能特点。结合两者的性能对比,更能清晰的认识两种材料的区分,更能清晰认识塑料改性的必要性。...
食品接触材料 高分子材料 食品模拟物中丙烯酰胺的测定 高效液相色谱法SNT 2282-2009 食品接触材料 高分子材料 食品模拟物中双酚A的测定 高效液相色谱法SNT 2284-2009 食品接触材料 高分子材料 总迁移量的测定方法 替代试验:用试验介质异辛烷和95%乙醇测定与脂肪类食品接触的塑料中的总迁移量SNT 2334-2009 食品接触材料 高分子材料 橄榄油中总迁移量的试验方法 全浸没法...
塑料(plastics):以树脂(resin)为主要成分,加入或不加入其他添加剂(填料、增塑剂、稳定剂、润滑剂、色料),所形成的高分子材料。合成的树脂为非天然获得的高分子材料。塑料、橡胶、纤维并称为世界三大有机高分子材料。其中,塑料的弹性模量介于橡胶和纤维之间,受力能发生一定形变。...
Copyright ©2007-2022 ANTPEDIA, All Rights Reserved
京ICP备07018254号 京公网安备1101085018 电信与信息服务业务经营许可证:京ICP证110310号